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Gossip Girl Off-Set Travel: Beware of Chuck

Spotted: A certain Upper East Sider going downtown to get lucky. Yup, that's Ed Westwick locked in an embrace with actress Drew Barrymore at a recent Kings of Leon concert at Webster Hall in New York.

While the Southern-fried band doesn't seem like the kind of music a Bass would really be able to rock out to, we're still hoping this scene is some kind of cameo. Would Chuck, force of destruction as he is, really go the cougar route right after his buddy Nate?

Adding to the mystery is the fact that Barrymore actually was spotted with Chace Crawford at last week's SNL afterparty. Sharing is for Brooklyn, boys!

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[Photo: I Don't Like You In That Way]